Flammable ice

This awesome little chemical machine is from Mr. Kent's chemistry page. Ice is laid in a Pyrex dish over a layer of calcium carbide. As the ice melts, the liquid water reacts with the carbide to produce acetylene gas, which of course is highly flammable. A match starts it off, and then it burns continuously on its own. My first thought was that the system could rapidly spiral out of control--more heat melts more water makes more gas makes even more heat. But it's limited by the amount of oxygen that can get down into the pan, I think. My second thought was that maybe a bit of sodium metal down there with the carbide could make the process self-igniting.... (For God's sake, no one try that.)


Recent Entries

Comments

Oldest comments listed first.

Posted by: Cayton Jones on October 29, 2009 at 7:20 PM

Sodium?

Psh, Cesium is where it's at.


Posted by: Bill Coleman on October 30, 2009 at 7:28 AM

Pyrex is no longer borosilicate glass

It is my understanding that after the company was sold, the new owners no longer made Pyrex from borosilicate (SP) glass, but instead make it from regular soda ash glass. So it is NOT safe to use it in this fashion, combining freezing
temps to boiling temps. Ok to go from room temps to the oven, but not safe to go from the freezer to the oven.

Be sure a and wear eye protection!


Posted by: Wilson! on October 30, 2009 at 8:23 AM

au contraire!

Well, it is MY understanding, from having worked in a lab for 10 of the last 12 years, that Corning/Pyrex LABORATORY glassware is still borosilicate. World Kitchen "Pyrex" for kitchen/home use is soda-ash since the sale of that division.


Posted by: Salviati on November 1, 2009 at 7:05 PM

Questions

If one were to re-create this experiment, do you have any advice on the ratios of Calcium Carbide to ice that should be used? I wouldn't want to add too much and risk fire, but I would like it to look impressive. Also, what grade of Calcium Carbide do you recommend?

To Bill and Wilson...What is the risk of using soda ash Pyrex rather than borosilicate? Is it more likely to break under the high heat? I don't suppose it would react with the chemicals, and I wouldn't intend on using it again for food. I've read that sand should be used to put out this reaction, but is there a problem with the standard A/B/C fire extinguisher?

Since Calcium Carbonate seems to be only available in 10+ lb batches, how would you recommend storing this chemical to ensure it stays potent and dry?

Thanks for the advice, and for the great video.


Leave a comment


Subscribe to MAKE!Subscribe to MAKE Magazine!

Subscribe today, save 42% and get web access to MAKE free. MAKE Digital Edition is available only to subscribers.

$34.95 / 1 year
(4 Quarterly Issues)

Subscribe now


Void your warranty, violate a user agreement, fry a circuit, blow a fuse, poke an eye out. Make: The risk-takers, the doers, the makers of things... Welcome to Make: Online!


CRAFT Maker Shed Maker Faire MAKE television
Holiday Gift Guides from MAKE
Gifts for Dads
Science and Chemistry
Gifts Under $20
More guides: Santa Claus Machines, Geek Toys for Grown Up Girls & Boys


Check out all of the episodes of Make: television

Alex Rider Dream Gadget Contest
Make: Science Room

Connect with MAKE

Be a MAKE fan on Facebook MAKE on Facebook
Visit our Facebook page and become a fan of MAKE!
MAKE on Twitter MAKE on Twitter
Follow our MAKE tweets!
MAKE Flickr Pool MAKE on Flickr
Join our MAKE Flickr Pool!
    make_tips on Twitter




    Maker SHED

    Advertise here with FM.

    Why advertise on MAKE?
    Read what folks are saying about us!

    Click here to advertise on MAKE!



    Subscribe to MAKE Magazine!

    Make: Online authors!

    Gareth BranwynGareth Branwyn
    Senior Editor


    Phillip TorronePhillip Torrone
    Senior Editor
    | AIM | Twitter


    Becky SternBecky Stern
    Associate Editor
    | AIM | Twitter


    Marc de VinckMarc de Vinck
    Contributing Writer
    | AIM | Twitter


    John ParkJohn Park
    Contributing Writer
    | Twitter


    Sean RaganSean Ragan
    Contributing Writer
    | Twitter


    Matt MetsMatt Mets
    Contributing Writer
    | AIM | Twitter


    Dale DoughertyDale Dougherty
    Editor & Publisher
    | Twitter


    Shawn ConnallyShawn Connally
    Managing Editor
    | Twitter


    Goli MohammadiGoli Mohammadi
    Associate Managing Editor

    Kip KayKip Kay
    Weekend Projects
    | AIM | Twitter


    Collin CunninghamCollin Cunningham
    Contributing Writer
    | AIM | Twitter

    Adam FlahertyAdam Flaherty
    Contributing Writer
    | AIM | Twitter



    More contributors: Mark Frauenfelder (Editor-in-Chief, MAKE magazine), Kipp Bradford (Technical Consultant/Writer), Chris Connors (Education), Diana Eng (Guest Author), Peter Horvath (Intern), Brian Jepson (O'Reilly Media), Robert Bruce Thompson (Science Room)

    Suggest a Site!

    Current Podcast

    itunesdl.gif Weekend Project: Beetlebot Simple robot from your parts bin that avoids obstacles. Thanks go to Jerome Demers for the original article in MAKE, Volume 12. To download the Beetlebot video, click here or subscribe in iTunes. Check out the complete Beetlebot article... More...

    Get the Make: Online sent via email
    Enter your email to receive Make: Online each day:



    MAKE Fascination video series brought to you by Dow

    Make: Education
    MAKE: en EspaƱol MAKE: Japan
    Important please read


    Subscribe to MAKE Magazine!

    Recent Posts from the Craft: Blog